Polarized light carries information about the various physical parameters that have been acting upon it. Obtaining information on the observed object by studying the polarization of light reflected can be done by several methods. The four Stokes parameters of the reflected light wave (S0, S1, S2 and S3) are generally estimated by observing the scene, with a CCD sensor, through a polarimeter. This device relies on acquisition of multiple frames relative to an adjustment parameter of the optical components: positioning angle or optical delay. In real time applications, the polarimeter often uses liquid crystal components. The adjustment retardation parameter is then controlled by an electric voltage. However, the retardation introduced by a liquid-crystal variable retarder (LCVR) is strongly dependent on temperature. One solution is to hold constant the LCVR temperature by using a thermostated environment but this is not always possible (power consumption in remote sensing for instance). In J. Opt. A: Pure Appl. Opt. 2, (2000), Bueno has showed that in this latter case it is necessary to calibrate the LCVR just before carrying out measurement and do this again approximately every ten minutes. In this article, we propose a robust and accurate solution, based on self-calibration principle, for measuring the Stokes parameters of partially linearly polarized. Unlike methods generally exposed in the literature, our polarization parameters estimation is independent of the accurate knowledge of the polarimeter variable retardations values and thus does not require a calibration process at regular intervals.